Pouch cell
In 1995, the pouch cell surprised the battery world with a radical new design. Rather than using a metallic cylinder and glass-to-metal electrical feed-through, conductive foil-tabs were welded to the electrodes and brought to the outside in a fully sealed way.
The pouch cell makes most efficient use of space and achieves 90–95 percent packaging efficiency, the highest among battery packs. Capacity is from 3.2V5Ah to 3.2V100Ah. Eliminating the metal enclosure reduces weight, but the cell needs support and allowance to expand in the battery compartment. The pouch packs are used in consumer, military, automotive ans solar energy applications. No standardized pouch cells exist, each manufacturer designs its own.
Pouch packs are commonly Li-polymer. Small cells such as are popular for portable applications requiring high load currents, such as drones and hobby gadgets. The larger cells in the 3.2V50Ah range serve in energy storage systems (ESS) because fewer cells simplify the battery design.
The technology has matured and prismatic and pouch cells have the potential for greater capacity than the cylindrical format. Large flat packs serve electric powertrains and Energy Storage System (ESS) with good results. The cost per kWh in the prismatic/pouch cell is still higher than with the 18650 cell but this is changing. Following picture compares the price of the cylindrical, prismatic and pouch cells, also known as laminated.
Prismatic Cell
Introduced in the early 1990s, the modern prismatic cell satisfies the demand for thinner sizes. Wrapped in elegant packages resembling a box of chewing gum or a small chocolate bar, prismatic cells make optimal use of space by using the layered approach. Prismatic cells are also available in large formats. Packaged in welded aluminum housings, the cells deliver capacities of 20–50Ah and are primarily used for electric powertrains in hybrid and electric vehicles.
The prismatic cell improves space utilization and allows flexible design but it can be more expensive to manufacture, less efficient in thermal management and have a shorter cycle life than the cylindrical design. Allow for some swelling.
The prismatic cell requires a firm enclosure to achieve compression. Some swelling due to gas buildup is normal, and growth allowance must be made; a 5mm (0.2”) cell can grow to 8mm (0.3”) after 500 cycles. Discontinue using the battery if the distortion presses against the battery compartment. Bulging batteries can damage equipment and compromise safety.
Cylindrical Cell
The cylindrical cell continues to be one of the most widely used packaging styles for primary and secondary batteries. The advantages are ease of manufacture and good mechanical stability. The tubular cylinder can withstand high internal pressures without deforming. The 18650 could well be the most optimized cell; it offers one of the lowest costs per Wh and has good reliability records.
The demand for the 18650 would have peaked in 2011 had it not been for new demands in military, medical and drones, including the Tesla electric car. The switch to a flat-design in consumer products and larger format for the electric powertrain will eventually saturate the 18650. A new entry is the 21700.Cell disintegration cannot always be prevented but propagation can. Cylindrical cells are often spaced apart to stop propagation should one cell take off. Spacing also helps in the thermal management. In addition, a cylindrical design does not change size. In comparison, a 5mm prismatic cell can expand to 8mm with use and allowances must be made.